Table 3 Values of \(\left( {K_{s}^{0} } \right)\), \(\left( {S_{K} } \right)\) \(\left( {K_{s,\upphi }^{0} } \right)\), \(\left( {S_{K,\upphi } } \right)\) and \(\left( {K_{s,\upphi , tr}^{0} } \right)\) for Asp in water, aqueous l-arabinose\(/\)d-xylose at 293.15 K, 298.15 K, 303.15, 308.15 K, 313.15 K and experimental pressure P = 101 kPa
Composition of solution | \({K}_{s}^{0}\)× \({10}^{10}\)/(\({\text{m}}^{2}{\text{N}}^{-1}\)) | \({S}_{K}\times {10}^{11}\)/(\({\text{m}}^{2}{\text{N}}^{-1}{\text{mol}}^{-1/2}{\text{kg}}^{1/2})\) | \(K_{s,\upphi }^{0}\)× \({10}^{13}\)/(\({\text{m}}^{5}{\text{mol}}^{-1}{\text{N}}^{-1}\)) | \(S_{k,\upphi }\) × 1012/(\({\text{m}}^{5}{\text{N}}^{-1}{\text{mol}}^{-3/2}{\text{kg}}^{1/2})\) | \(\Delta_{tr} K_{s,\upphi }^{0}\) × 1013/(\({\text{m}}^{5}{\text{mol}}^{-1}{\text{N}}^{-1}\)) |
|---|---|---|---|---|---|
293.15 K | |||||
 Water | 5.75 \(\pm\) 0.01 | − 3.74 \(\pm\) 0.18 | −5.75 \(\pm\) 0.84 | 2.04 \(\pm\) 0.48 |  |
 Aq l-arabinose | |||||
2.0 wt % | 4.48 \(\pm\) 0.01 | − 3.77 \(\pm\) 0.21 | − 4.98 \(\pm\) 0.93 | 1.74 \(\pm\) 0.22 | 0.77 |
2.5 wt % | 4.44 \(\pm\) 0.01 | − 3.71 \(\pm\) 0.13 | − 4.93 \(\pm\) 0.48 | 1.72 \(\pm\) 0.53 | 0.81 |
3.0 wt % | 4.42 \(\pm\) 0.01 | − 3.68 \(\pm\) 0.05 | − 4.88 \(\pm\) 0.75 | 1.71 \(\pm\) 0.57 | 0.87 |
 Aq d-xylose | |||||
2.0 wt % | 4.47 \(\pm\) 0.01 | − 3.74 \(\pm\) 0.21 | − 5.02 \(\pm\) 0.72 | 1.75 \(\pm\) 0.53 | 0.73 |
2.5 wt % | 4.44 \(\pm\) 0.03 | − 3.70 \(\pm\) 0.18 | − 4.97 \(\pm\) 0.72 | 1.74 \(\pm\) 0.28 | 0.78 |
3.0 wt % | 4.41 \(\pm\) 0.01 | − 3.66 \(\pm\) 0.76 | − 4.91 \(\pm\) 0.76 | 1.71 \(\pm\) 0.44 | 0.84 |
298.15 K | |||||
 Water | 4.50 \(\pm\) 0.01 | − 3.73 \(\pm\) 0.36 | − 5.64 \(\pm\) 0.83 | 1.87 \(\pm\) 0.48 |  |
 Aq l-arabinose | |||||
2.0 wt % | 4.48 ± 0.01 | − 3.74 ± 0.03 | − 4.84 ± 0.07 | 1.47 ± 0.04 | 0.80 |
2.5 wt % | 4.36 ± 0.01 | − 3.61 ± 0.68 | − 4.80 ± 1.11 | 1.46 ± 0.60 | 0.84 |
3.0 wt % | 4.33 ± 0.01 | − 3.59 ± 0.10 | − 4.74 ± 0.59 | 1.45 ± 0.39 | 0.90 |
 Aq d-xylose | |||||
2.0 wt % | 4.40 ± 0.01 | − 3.67 ± 0.21 | − 5.15 ± 0.21 | 1.67 ± 0.18 | 0.49 |
2.5 wt % | 4.37 ± 0.01 | − 3.64 ± 0.53 | − 4.94 ± 0.83 | 1.48 ± 0.41 | 0.69 |
3.0 wt % | 4.34 ± 0.01 | − 3.61 ± 0.51 | − 4.87 ± 0.33 | 1.50 ± 0.48 | 0.77 |
303.15 K | |||||
 Water | 4.45 \(\pm\) 0.01 | − 3.70 \(\pm\) 0.36 | − 5.45 \(\pm\) 0.83 | 1.77 \(\pm\) 0.48 |  |
 Aq l-arabinose | |||||
2.0 wt % | 4.38 ± 0.01 | − 3.72 ± 0.03 | − 5.18 ± 0.07 | 1.85 ± 0.04 | 0.27 |
2.5 wt % | 4.35 ± 0.01 | − 3.69 ± 0.68 | − 5.13 ± 1.11 | 1.83 ± 0.60 | 0.32 |
3.0 wt % | 4.32 ± 0.01 | − 3.66 ± 0.10 | − 5.07 ± 0.59 | 1.81 ± 0.39 | 0.38 |
 Aq d-xylose | |||||
2.0 wt % | 4.39 ± 0.01 | − 3.75 ± 0.21 | − 5.22 ± 0.21 | 1.86 ± 0.18 | 0.22 |
2.5 wt % | 4.35 ± 0.01 | − 3.70 ± 0.53 | − 5.16 ± 0.83 | 1.84 ± 0.41 | 0.29 |
3.0 wt % | 4.32 ± 0.01 | − 3.68 ± 0.51 | − 5.11 ± 0.33 | 1.82 ± 0.48 | 0.34 |
308.15 K | |||||
 Water | 4.41 \(\pm\) 0.01 | − 3.70 \(\pm\) 0.36 | − 8.61 \(\pm\) 0.83 | 3.29 \(\pm\) 0.48 |  |
 Aq l-arabinose | |||||
2.0 wt % | 4.34 ± 0.01 | − 3.65 ± 0.03 | − 5.10 ± 0.07 | 1.82 ± 0.04 | 3.51 |
2.5 wt % | 4.30 ± 0.01 | − 3.62 ± 0.68 | − 5.04 ± 1.11 | 1.80 ± 0.60 | 3.57 |
3.0 wt % | 4.27 ± 0.01 | − 3.60 ± 0.10 | − 5.00 ± 0.59 | 1.79 ± 0.39 | 3.58 |
 Aq d-xylose | |||||
2.0 wt % | 4.34 ± 0.01 | − 3.69 ± 0.21 | − 5.15 ± 0.21 | 1.84 ± 0.18 | 3.46 |
2.5 wt % | 4.31 ± 0.01 | − 3.64 ± 0.53 | − 5.07 ± 0.83 | 1.81 ± 0.41 | 3.54 |
3.0 wt % | 4.28 ± 0.01 | − 3.61 ± 0.51 | − 5.04 ± 0.33 | 1.80 ± 0.48 | 3.57 |
313.15 K | |||||
 Water | 4.41 \(\pm\) 0.01 | − 3.01 \(\pm\) 0.36 | − 13.47 \(\pm\) 0.83 | 5.33 \(\pm\) 0.48 |  |
 Aq l-arabinose | |||||
2.0 wt % | 4.28 ± 0.01 | − 3.59 ± 0.03 | − 5.01 ± 0.07 | 1.79 ± 0.04 | 8.46 |
2.5 wt % | 4.25 ± 0.01 | − 3.56 ± 0.68 | − 4.96 ± 1.11 | 1.76 ± 0.60 | 8.51 |
3.0 wt % | 4.22 ± 0.01 | − 3.53 ± 0.10 | − 4.91 ± 0.59 | 1.78 ± 0.39 | 8.56 |
 Aq d-xylose | |||||
2.0 wt % | 4.29 ± 0.01 | − 3.63 ± 0.21 | − 5.07 ± 0.21 | 1.81 ± 0.18 | 8.40 |
2.5 wt % | 4.26 ± 0.01 | − 3.58 ± 0.53 | − 5.00 ± 0.83 | 1.79 ± 0.41 | 8.47 |
3.0 wt % | 4.23 ± 0.01 | − 3.55 ± 0.51 | − 4.91 ± 0.33 | 1.76 ± 0.48 | 8.56 |