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Table 1 Chemical profiles of the volatile oils of A. annua, A. herba-alba, A. monosperma and A. judaica

From: Comparative phytochemical profiling and authentication of four Artemisia species using integrated GC-MS, HPTLC and NIR spectroscopy approach

No.

Compounds

Rt

RI

A. annua

A. herba-alba

A. monosperma

A. judaica

1

Santolina Triene

7.44

911

-

0.53

-

-

2

α-thujene

8.03

929

0.19

0.15

0.65

0.16

3

α-pinene

8.1

933

0.54

3.27

9.39

0.45

4

Camphene

8.55

947

1.15

9.03

-

1.01

5

Thuja-2,4(10)-diene

8.81

954

-

0.87

-

-

6

Sabinene

9.37

972

1.54

4.88

-

1.27

7

β-pinene

9.73

984

0.24

0.41

13.95

0.22

8

β-Myrcene

9.9

989

0.46

0.66

5.28

0.37

9

Yomogi Alcohol

10.14

998

0.44

1.92

-

0.37

10

α-phellandrene

10.24

1001

-

-

0.74

-

11

δ-3-carene

10.31

1004

-

-

1.74

0.18

12

α-terpinene

10.69

1015

0.29

2.26

-

-

13

P-cymene

10.93

1022

2.23

2.55

-

1.77

14

trans-2,7-Dimethyl-4,6-octadien-2-ol

11.01

1025

-

1.82

-

-

15

Limonene

11.1

1028

-

-

5.42

-

16

1,8-Cineole (Eucalyptol)

11.19

1031

5.33

3.61

-

4.54

17

Cis-β-Ocimene

11.42

1038

-

-

4

-

18

7-Methylbicyclo [2.2.1] hept-5-en-2-one

11.43

1039

-

0.7

-

-

19

Trans-β-Ocimene

11.72

1047

-

-

3.59

0.4

20

γ-Terpinene

11.98

1056

0.55

1.39

1.21

-

21

Artemisia ketone

12.13

1061

3.02

-

-

2.54

22

Artemisia Alcohol

12.69

1079

0.55

0.51

-

0.47

23

α-terpinolene

12.85

1084

-

-

13.61

-

24

Linalool

13.31

1098

0.38

-

-

0.29

25

α-thujone

13.51

1105

0.86

2.17

-

0.61

26

β-thujone

13.77

1113

-

0.24

-

-

27

Chrysanthenone

13.96

1120

-

0.52

0.14

-

28

Cis-Verbenol

14.25

1129

-

0.3

-

-

29

Trans-p-2-Menthen-1-ol

14.26

1129

-

-

0.3

-

30

Camphor

14.64

1142

26.45

0.49

-

23.19

31

Lavandulol

15.25

1162

0.42

0.21

-

0.41

32

Borneol

15.31

1163

3.91

0.27

-

3.84

33

Terpinen-4-ol

15.62

1173

1.09

0.17

1.55

1.13

34

Cis-Pinocarveol

15.95

1183

-

22.6

-

-

35

α-terpineol

16.21

1191

0.2

0.13

0.17

0.23

36

Myrtenol

16.43

1198

-

1.05

-

-

37

Cis-piperitol

16.5

1200

-

4.12

-

-

38

n-Decanal

17.2

1223

-

-

0.37

-

39

Dihydrocarvone

17.65

1237

0.18

-

-

-

40

Verbenone

18.5

1264

0.66

-

-

-

41

Linalyl acetate

18.58

1267

-

-

0.21

0.63

42

p-cymen-9-ol

18.67

1270

0.74

-

0.29

0.77

43

Thymol

19.1

1284

0.66

-

2.27

0.7

44

Trans-Chrysanthenyl acetate

19.61

1300

-

13.88

-

-

45

Cuminaldehyde

19.84

1307

0.19

0.12

-

0.16

46

Cis-Chrysanthenyl acetate

20.36

1324

-

9.35

0.33

-

47

Piperitone

20.45

1327

-

-

-

17.14

48

α-Copaene

22.34

1387

0.83

-

-

0.9

49

β-Cubebene

22.45

1391

0.22

-

-

0.26

50

β-Elemene

22.76

1400

0.44

0.77

0.62

0.34

51

Cyperene

22.97

1407

-

0.37

-

-

52

Cis-threo-Davanafuran

23.38

1420

-

-

1.06

-

53

β-Caryophyllene

23.62

1428

17.75

0.33

0.19

-

54

Geranyl acetone

24.08

1443

-

-

0.25

-

55

α-Humulene

24.32

1450

0.42

-

0.13

0.37

56

Trans-β-Farnesene

24.59

1459

5.72

-

-

6.87

57

α-curcumene

25.12

1476

-

-

2.78

-

58

Cis-muurola-4(14),5-diene

25.23

1479

-

1.15

-

-

59

Trans-Ethyl cinnamate

25.24

1480

-

-

-

12.65

60

Germacrene D

25.28

1483

9.81

-

2.04

-

61

α-Selinene

25.39

1487

2.88

-

-

4.04

62

β-Bisabolene

25.53

1492

-

-

-

0.81

63

γ-Amorphene

25.54

1493

0.63

-

-

-

64

α-muurolene

25.64

1497

-

0.48

1.08

-

65

δ-Cadinene

25.92

1506

0.21

0.34

0.43

-

66

Isoshyobunone

26.32

1518

-

-

2.68

-

67

Calamenene

26.71

1530

-

-

0.98

-

68

α-Calacorene

26.83

1534

-

-

1.54

-

69

Widdrol

26.93

1538

-

-

1.76

-

70

Nerolidol

27.03

1543

-

-

-

0.17

71

Citronellyl isovalerate

27.1

1547

-

-

1.52

-

72

Germacrene D-4-ol

27.3

1551

1.16

-

-

1.43

73

(-)-Spathulenol

27.5

1558

0.78

0.26

11.71

0.96

74

Davanone

27.95

1573

-

-

1.08

-

75

Caryophyllene oxide

28.37

1584

0.5

2.91

-

0.62

76

Carotol

28.61

1593

-

-

0.13

-

77

1-epi-Cubenol

28.74

1599

1.91

-

-

2.56

78

epi-α-Cadinol

29.05

1611

-

-

0.15

-

79

α-Muurolol

29.21

1617

0.59

-

0.33

0.63

80

8-Isopropenyl-1,3,3,7-tetramethyl-bicyclo[5.1.0]-oct-5-en-2-one

29.37

1619

0.6

-

-

0.67

81

γ-Gurjunene epoxide

29.43

1621

-

0.81

-

-

82

α-Humulene epoxide II

29.5

1625

-

-

0.72

-

83

β-Eudesmol

29.64

1629

-

-

1.35

-

84

α-Cadinol

29.87

1632

0.44

0.14

0.59

0.57

85

β-bisabolol

29.93

1635

-

-

0.43

-

86

Cedr-8-en-13-ol

30.15

1641

0.26

-

-

0.2

87

9H-Cycloisolongifolene, 8-oxo-

30.5

1653

-

-

-

0.2

88

1-Methylene-2b-hydroxymethyl-3,3-dimethyl-4b-(3-methylbut-2-enyl)-cyclohexane

31.07

1675

0.52

-

-

0.57

89

Isolongifolol

31.25

1681

0.28

0.17

-

0.29

90

β-Santalol

31.65

1693

0.4

0.23

0.13

0.48

91

Auraptenol

34.68

1792

0.8

-

-

0.95

92

Phytol

37.92

1899

0.4

-

-

0.4

 

Total identified

  

99.79%

98.89%

98.14%

99.82%

 

Monoterpene hydrocarbons

  

7.19%

26%

59.58%

5.83%

 

Oxgyenated monoterpenes

  

45.08%

63.48%

5.18%

57.04%

 

Sesquiterpene hydrocarbons

  

38.91%

3.44%

9.79%

13.59%

 

Oxgyenated sesquiterpenes

  

7.44%

4.52%

22.58%

9.35%

 

Non-terpenoid compounds

  

0.8%

0.7%

1.43%

13.6%

 

Oxgyenated Diterpenes

  

0.4%

-

-

0.4%

  1. Rt, retention time (min.); RI, retention index on TG-5MS column relative to n-alkanes (C5-C28); Identification of compounds based on MS and RI by comparison to the NIST, WILEY and ADAMS libraries; Quantity of identified compounds presented as % relative peak area