Unraveling the effect of choline-based choline based ionic liquids on the physicochemical properties and taste behavior of D( +)-glucose in aqueous solutions

Dorosti, Sara; Shekaari, Hemayat; Bagheri, Mohammad; Ghaffari, Fariba; Mokhtarpour, Masumeh

doi:10.1186/s13065-025-01407-3

Table 6 The values of speed of sound, u, and apparent molar isentropic compressibility, \(\kappa_{\varphi }\), for D( +)-glucose in the aqueous ILs solutions at different temperature and P = 0.0871 MPa. ^a

From: Unraveling the effect of choline-based choline based ionic liquids on the physicochemical properties and taste behavior of D( +)-glucose in aqueous solutions

m (mol·kg⁻¹)	u (m·s⁻¹)					10¹⁴ κ_φ (m³·mol⁻¹·Pa⁻¹)
T (K)	298.15	303.15	308.15	313.15	318.15	298.15	303.15	308.15	313.15	318.15
D( +)-glucose in water
0.0000	1496.96	1509.44	1520.15	1529.23	1536.73	–	–	–	–	–
0.0250	1498.42	1510.90	1521.61	1530.69	1538.19	− 1.73	− 1.66	− 1.61	− 1.57	− 1.55
0.0500	1499.90	1512.38	1523.09	1532.17	1539.67	− 1.71	− 1.65	− 1.60	− 1.56	− 1.53
0.0741	1501.35	1513.83	1524.54	1533.62	1541.12	− 1.69	− 1.64	− 1.60	− 1.55	− 1.52
0.1001	1502.91	1515.39	1526.10	1535.18	1542.68	− 1.68	− 1.61	− 1.57	− 1.53	− 1.50
0.1249	1504.45	1516.93	1527.64	1536.72	1544.22	− 1.67	− 1.60	− 1.55	− 1.52	− 1.50
0.1498	1506.01	1518.49	1529.20	1538.28	1545.78	− 1.65	− 1.60	− 1.55	− 1.51	− 1.49
D( +)-glucose in aqueous solutions of [Ch][Sal] (0.0305 mol·kg⁻¹)
0.0000	1500.37	1512.32	1522.67	1531.46	1538.76	–	–	–	–	–
0.0252	1501.97	1513.88	1524.20	1532.90	1540.14	− 1.84	− 1.69	− 1.57	− 1.32	− 1.17
0.0503	1503.53	1515.38	1525.60	1534.30	1541.48	− 1.80	− 1.62	− 1.41	− 1.28	− 1.11
0.0750	1505.08	1516.84	1526.99	1535.64	1542.78	− 1.79	− 1.57	− 1.36	− 1.22	− 1.08
0.1003	1506.68	1518.39	1528.48	1537.00	1544.03	− 1.78	− 1.57	− 1.37	− 1.18	− 1.01
0.1247	1508.19	1519.81	1529.83	1538.35	1545.32	− 1.76	− 1.54	− 1.33	− 1.17	− 1.00
0.1500	1509.60	1521.31	1531.38	1539.62	1546.49	− 1.68	− 1.52	− 1.36	− 1.11	− 0.93
D( +)-glucose in aqueous solutions of [Ch][Sal] (0.0600 mol·kg⁻¹)
0.0000	1503.98	1515.71	1525.77	1534.30	1541.37	–	–	–	–	–
0.0250	1505.56	1517.22	1527.24	1535.71	1542.73	− 1.79	− 1.56	− 1.42	− 1.25	− 1.11
0.0500	1507.13	1518.72	1528.66	1537.11	1544.10	− 1.77	− 1.54	− 1.35	− 1.22	− 1.10
0.075	1508.67	1520.20	1530.10	1538.52	1545.41	− 1.73	− 1.51	− 1.34	− 1.22	− 1.04
0.0999	1510.22	1521.67	1531.52	1539.89	1546.71	− 1.72	− 1.48	− 1.31	− 1.18	− 1.01
0.1248	1511.77	1523.26	1533.17	1541.30	1548.03	− 1.71	− 1.52	− 1.40	− 1.18	− 1.00
0.1499	1513.29	1524.65	1534.34	1542.60	1549.21	− 1.68	− 1.46	− 1.27	− 1.13	− 0.92
D( +)-glucose in aqueous solutions of [Ch][Sal] (0.0900 mol·kg⁻¹)
0.0000	1507.38	1518.87	1528.80	1537.10	1544.20	–	–	–	–	–
0.0250	1509.00	1520.45	1530.32	1538.57	1545.61	− 1.84	− 1.69	− 1.50	− 1.35	− 1.19
0.0491	1510.57	1521.93	1531.75	1539.92	1546.92	− 1.84	− 1.62	− 1.45	− 1.26	− 1.11
0.0745	1512.14	1523.44	1533.19	1541.32	1548.23	− 1.77	− 1.55	− 1.37	− 1.20	− 1.03
0.0999	1513.72	1524.99	1534.60	1542.71	1549.56	− 1.73	− 1.54	− 1.31	− 1.16	− 0.99
0.1244	1515.22	1526.39	1535.98	1544.00	1550.81	− 1.69	− 1.48	− 1.28	− 1.12	− 0.95
0.1499	1516.80	1527.80	1537.33	1545.15	1551.73	− 1.67	− 1.42	− 1.23	− 1.01	− 0.78
D( +)-glucose in aqueous solutions of [Ch][For] (0.0297 mol·kg⁻¹)
0.0000	1498.99	1511.75	1523.20	1532.85	1541.75	–	–	–	–	–
0.0251	1500.72	1513.40	1524.77	1534.33	1543.13	− 2.33	− 2.04	− 1.77	− 1.51	− 1.23
0.0504	1502.41	1515.06	1526.38	1535.79	1544.49	− 2.24	− 2.01	− 1.77	− 1.44	− 1.17
0.0752	1504.12	1516.63	1527.74	1537.18	1545.78	− 2.22	− 1.91	− 1.58	− 1.36	− 1.10
0.1003	1505.56	1518.12	1529.22	1538.41	1547.01	− 2.02	− 1.81	− 1.53	− 1.22	− 1.01
0.1252	1507.13	1519.59	1530.52	1539.71	1548.21	− 1.97	− 1.73	− 1.42	− 1.15	− 0.94
0.1499	1508.74	1520.91	1531.76	1540.86	1549.16	− 1.93	− 1.61	− 1.31	− 1.06	− 0.79
D( +)-glucose in aqueous solutions of [Ch][For] (0.0600 mol·kg⁻¹)
0.0000	1501.24	1513.25	1523.97	1534.08	1543.78	–	–	–	–	–
0.0252	1502.82	1514.78	1525.46	1535.53	1545.19	− 1.83	− 1.65	− 1.49	− 1.34	− 1.21
0.0501	1504.39	1516.31	1526.93	1536.93	1546.53	− 1.83	− 1.65	− 1.47	− 1.30	− 1.14
0.0751	1505.95	1517.80	1528.40	1538.38	1547.89	− 1.80	− 1.61	− 1.45	− 1.30	− 1.11
0.1001	1507.46	1519.23	1529.79	1539.69	1549.21	− 1.75	− 1.54	− 1.38	− 1.21	− 1.06
0.1248	1508.92	1520.75	1531.18	1541.11	1550.55	− 1.69	− 1.54	− 1.35	− 1.20	− 1.04
0.1502	1510.56	1522.20	1532.68	1542.47	1551.81	− 1.70	− 1.49	− 1.34	− 1.17	− 0.99
D( +)-glucose in aqueous solutions of [Ch][For] (0.0900 mol·kg⁻¹)
0.0000	1503.28	1515.47	1526.11	1535.27	1542.86	–	–	–	–	–
0.0253	1504.91	1517.03	1527.60	1536.68	1544.21	− 1.88	− 1.65	− 1.43	− 1.20	− 1.02
0.0498	1506.45	1518.52	1529.05	1538.06	1545.49	− 1.82	− 1.62	− 1.43	− 1.20	− 0.98
0.0747	1508.07	1520.02	1530.46	1539.39	1546.79	− 1.83	− 1.58	− 1.37	− 1.15	− 0.96
0.0999	1509.67	1521.50	1531.91	1540.77	1548.06	− 1.83	− 1.55	− 1.36	− 1.14	− 0.93
0.1245	1511.14	1522.97	1533.22	1542.05	1549.32	− 1.77	− 1.53	− 1.29	− 1.10	− 0.91
0.1497	1512.73	1524.46	1534.74	1543.33	1550.58	− 1.75	− 1.51	− 1.31	− 1.05	− 0.89
D( +)-glucose in aqueous solutions of [Ch][Ace] (0.0299 mol·kg⁻¹)
0.0000	1500.33	1512.35	1522.80	1531.81	1538.97	–	–	–	–	–
0.0254	1501.93	1513.89	1524.24	1533.16	1540.20	− 1.82	− 1.62	− 1.34	− 1.11	− 0.83
0.0499	1503.46	1515.35	1525.59	1534.36	1541.35	− 1.79	− 1.58	− 1.29	− 0.99	− 0.77
0.0752	1505.02	1516.86	1527.01	1535.64	1542.56	− 1.76	− 1.56	− 1.28	− 0.96	− 0.77
0.1000	1506.55	1518.32	1528.41	1536.92	1543.74	− 1.73	− 1.53	− 1.28	− 0.96	− 0.75
0.1251	1508.08	1519.78	1529.82	1538.22	1544.94	− 1.71	− 1.50	− 1.27	− 0.96	− 0.75
0.1500	1509.58	1521.22	1531.21	1539.57	1546.08	− 1.68	− 1.48	− 1.26	− 0.98	− 0.72
D( +)-glucose in aqueous solutions of [Ch][Ace] (0.0600 mol·kg⁻¹)
0.0000	1503.59	1515.49	1525.71	1534.32	1541.58	–	–	–	–	–
0.0257	1505.21	1517.05	1527.19	1535.74	1542.93	− 1.80	− 1.61	− 1.38	− 1.21	− 1.03
0.0499	1506.73	1518.45	1528.60	1537.07	1544.16	− 1.78	− 1.51	− 1.39	− 1.19	− 0.97
0.0750	1508.28	1519.93	1529.97	1538.42	1545.46	− 1.75	− 1.49	− 1.31	− 1.15	− 0.97
0.0997	1509.81	1521.37	1531.38	1539.77	1546.76	− 1.72	− 1.47	− 1.31	− 1.14	− 0.97
0.1248	1511.32	1522.84	1532.81	1541.15	1548.07	− 1.69	− 1.45	− 1.30	− 1.14	− 0.96
0.1500	1512.85	1524.33	1534.17	1542.53	1549.40	− 1.66	− 1.45	− 1.26	− 1.13	− 0.96
D( +)-glucose in aqueous solutions of [Ch][Ace] (0.0900 mol·kg⁻¹)
0.0000	1507.04	1518.69	1528.76	1537.15	1544.16	–	–	–	–	–
0.0250	1508.56	1520.16	1530.18	1538.52	1545.46	− 1.63	− 1.45	− 1.29	− 1.14	− 0.96
0.0502	1510.08	1521.63	1531.60	1539.86	1546.77	− 1.61	− 1.43	− 1.27	− 1.09	− 0.94
0.0750	1511.58	1523.06	1532.99	1541.20	1548.06	− 1.60	− 1.40	− 1.25	− 1.08	− 0.94
0.1000	1513.10	1524.56	1534.41	1542.56	1549.37	− 1.59	− 1.42	− 1.25	− 1.08	− 0.94
0.1249	1514.61	1526.02	1535.78	1543.92	1550.66	− 1.58	− 1.41	− 1.22	− 1.08	− 0.93
0.1496	1516.12	1527.42	1537.18	1545.28	1551.97	− 1.58	− 1.38	− 1.22	− 1.08	− 0.93

^aThe standard uncertainties for molality, temperature and pressure were u (m) = 0.001 mol kg⁻¹, u (T) = 0.2 K, u (P) = 10.5 hPa, respectively with level of confidence 0.95. The standard combined uncertainty for speed of sound and apparent molar compressibility were estimated to be, u_c (u) = 1.5 m s⁻¹ and u_c(κ_φ) = 3.10^–13 m³ mol·Pa⁻¹ (level of confidence 0.68), respectively

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