Table 5 The standard apparent molar expansibility (\(E_{\varphi }^{0}\)), thermal expansion coefficient (\(\alpha\)), Hepler's constant \((\partial^{2} V_{\varphi }^{0} /\partial T^{2} )_{P}\) of D( +)-glucose in water and in the aqueous ionic liquids solutions at T = (298.15 to 318.15) K and under atmospheric pressurea
T/K | Eφ0 (m3·mol−1·K−1) | 103 \(\alpha (\) K−1) | 102 \((\partial^{2} V_{\varphi }^{0} /\partial T^{2} )_{P}\) |
|---|---|---|---|
D( +)-glucose in water | |||
298.15 | 0.057 | 5.20 | − 0.0200 |
303.15 | 0.057 | 5.15 | |
308.15 | 0.056 | 5.10 | |
313.15 | 0.056 | 5.05 | |
318.15 | 0.055 | 4.99 | |
D( +)-glucose in aqueous solutions of [Ch][Sal] (0.0298 mol.kg−1) | |||
298.15 | 0.065 | 5.81 | − 4.2600 |
303.15 | 0.063 | 5.60 | |
308.15 | 0.061 | 5.40 | |
313.15 | 0.058 | 5.19 | |
318.15 | 0.056 | 4.99 | |
D( +)-glucose in aqueous solutions of [Ch][Sal] (0.0606 mol.kg−1) | |||
298.15 | 0.058 | 5.18 | 5.3000 |
303.15 | 0.061 | 5.40 | |
308.15 | 0.063 | 5.63 | |
313.15 | 0.066 | 5.84 | |
318.15 | 0.069 | 6.06 | |
D( +)-glucose in aqueous solutions of [Ch][Sal] (0.0901 mol.kg−1) | |||
298.15 | 0.061 | 5.48 | 5.7000 |
303.15 | 0.064 | 5.72 | |
308.15 | 0.067 | 5.96 | |
313.15 | 0.070 | 6.19 | |
318.15 | 0.073 | 6.42 | |
D( +)-glucose in aqueous solutions of [Ch][For] (0.0305 mol.kg−1) | |||
298.15 | 0.118 | 10.7 | − 0.0010 |
303.15 | 0.109 | 9.89 | |
308.15 | 0.101 | 9.092 | |
313.15 | 0.093 | 8.311 | |
318.15 | 0.084 | 7.536 | |
D( +)-glucose in aqueous solutions of [Ch][For] (0.0595 mol.kg−1) | |||
298.15 | 0.077 | 6.881 | − 0.0002 |
303.15 | 0.075 | 6.735 | |
308.15 | 0.074 | 6.588 | |
313.15 | 0.072 | 6.445 | |
318.15 | 0.071 | 6.302 | |
D( +)-glucose in aqueous solutions of [Ch][For] (0.0895 mol.kg−1) | |||
298.15 | 0.062 | 5.522 | 0.0011 |
303.15 | 0.067 | 6.006 | |
308.15 | 0.073 | 6.487 | |
313.15 | 0.079 | 6.959 | |
318.15 | 0.084 | 7.431 | |
D( +)-glucose in aqueous solutions of [Ch][Ace] (0.0298 mol.kg−1) | |||
298.15 | 0.059 | 5.302 | − 0.0021 |
303.15 | 0.049 | 4.355 | |
308.15 | 0.038 | 3.414 | |
313.15 | 0.028 | 2.477 | |
318.15 | 0.017 | 1.543 | |
D( +)-glucose in aqueous solutions of [Ch][Ace] (0.0599 mol.kg−1) | |||
298.15 | 0.048 | 4.328 | − 0.0002 |
303.15 | 0.047 | 4.233 | |
308.15 | 0.047 | 4.140 | |
313.15 | 0.046 | 4.046 | |
318.15 | 0.045 | 3.954 | |
D( +)-glucose in aqueous solutions of [Ch][Ace] (0.0897 mol.kg−1) | |||
298.15 | 0.060 | 5.319 | − 0.0006 |
303.15 | 0.056 | 5.018 | |
308.15 | 0.053 | 4.723 | |
313.15 | 0.05 | 4.427 | |
318.15 | 0.047 | 4.134 | |