Table 5 Synthesis of 7(a–j) by MTPPBr-PHTH-DES
| |||||||
|---|---|---|---|---|---|---|---|
Entry | Aldehyde | Product | Time (min) | Yield (%) | M.P. °C Found, literature | TON | TOF |
1 |
| 7a | 10 | 95 | 262-265, 256-257 [48] | 95 | 9.50 |
2 |
| 7b | 15 | 97 | 263-267, 266–268 [49] | 97 | 6.46 |
3 |
| 7c | 10 | 96 | 259-262, 264-267 [49] | 96 | 9.60 |
4 |
| 7d | 20 | 93 | 260-263, 256-258 [49] | 93 | 4.65 |
5 |
| 7e | 10 | 92 | 256-258, 261-263 [49] | 92 | 9.20 |
6 |
| 7f | 10 | 90 | 273-275, 259-261 [49] | 90 | 9.00 |
7 |
| 7g | 20 | 91 | 234-236, 230-233 [50] | 91 | 4.55 |
8 |
| 7h | 25 | 85 | 230-233, 233-236 [50] | 85 | 3.40 |
9 |
| 7i | 20 | 88 | 248-252, 260–263 [51] | 88 | 4.40 |
10 |
| 7j | 25 | 89 | 220-224, 226-230 [48] | 89 | 3.56 |
