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Table 8 Thermal decomposition gas products of BHTOOH identified by GC–MS under three gaseous atmospheres

From: Thermal decomposition characteristics of BHT and its peroxide (BHTOOH)

No.

Components

Molecular formula

Relative content %

Similarity %

N2

O2

Aira

Airb

1

Oxygen

O2

0.18

58.2

54.4

57.4

92

2

Nitrogen

N2

60.7

–

–

–

93

3

Water

H2O

8.30

3.88

4.48

4.98

100

4

Methyl formate

C2H4O2

1.29

1.04

0.51

0.58

99

5

Acetone

C3H6O

0.34

8.32

15.8

18.7

98

6

Ethyl formate

C3H6O2

0.07

0.74

1.12

 

92

7

Isobutylene

C4H8

28.0

27.2

23.4

17.6

97

8

tert-Butanol

C4H10O

0.73

0.40

0.35

0.55

97

9

Isobutyraldehyde

C4H8O

0.09

–

–

–

92

10

Pivalaldehyde

C5H10O

0.27

0.23

0.06

0.23

93

  1. aNo gas filling
  2. bP0 = 0.4 MPa